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Dark patches on internal chimney wall

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I had a couple of dark patches so the wall was taken back to brick. No signs of damp, no rotten skirting, no signs of water through concrete floor. Chimney is not used and ventilated. Treated for salts and then recovered left to dry. Painted with zinzer bin several coats per instructions then Matt emulsion. Used a dehumidifier in the winter in case of condensation as it’s a cold wall. Dark patches have reappeared in places. Any help or advice would be appreciated. Sorry I am not very good at diy but I have been reading that zinzer cover stain may be better as it is oil based?
0% credit card £1360 & 0% Car Loan £7500 ~ paid in full JAN 2020 = NOW DEBT FREE 🤗
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House purchase completed FEB 2023 🥳🍾 Left work. 🤗

Retired at 55 & now living off the equity £10k a year (until pensions start at 60 & 67).

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