Can a Power of Attorney assume the role of Executor of Will for elderly relative?

My very elderly mother has discovered she is Executor of her deceased brothers Will. She is almost 90 and will not be able to cope with this. I have Power of Attorney for her so can I help her and take over her duties? If so is there something I must do to make this legal?
:hello: “Life is not measured by the number of breaths we take, but by the moments that take our breath away” anon.
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