Claiming tax relief - higher rate

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In tax year 2021 - 2022 and again in the current ta x year, due to overtime at work and doing agency work, I have tipped into the higher income tax bracket - not by much but enough to end up owing around £300 for tax year 2021-2022. This has been reclaimed by HMRC over the current tax year via an alteration of my tax code.
My question is am I able to regain some of this with claiming the higher rate tax relief on my pension? I am currently enrolled in the NHS pension which deducts from my monthly wage. I am also enrolled in the pension provided by the agency I work for. In both jobs I am taxed at the basic and intermediate rates (based in Scotland).
Could anyone advise of the procedure to reclaim this tax relief? If it is applicable that is. The thought of spending a lengthy period of time on the hmrc helpline is not appealing - and the labrynith that is their website - hsa proven far from useful.. If I am entitled to the relief - is it paid directly to one of my pensions?
Thanks in advance.
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The NHS scheme is "net pay" so you automatically receive the maximum possible tax saving each payday.
With the pension with the agency job, what method was used to get money into it?
The normal methods are,
Net pay
For the last year, it seems HMRC reckon you under paid by £300. Why do you think that's incorrect, is ther something they didn't account for? There are various options for reviewing past years, I've not used these as I always need to do a return.
https://www.gov.uk/claim-tax-refund
There is nothing to claim from HMRC and you don't need to do anything, you get the maximum tax savings just by the contribution reducing your taxable income.
You could make separate contributions to a personal pension or SIPP to further reduce your liability you will be higher rate again this tax year but there is nothing you can do to change what's happened in 2021:22.