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White Linen Trousers - black mark

Hi I've a pair of white linen trousers which I have worn once. Washed according to the instructions, hung them out to dry and when I got them off the line there was a black mark which definitely wasn't there when it was hung out :(

I always wipe the line before pegging out, the pegs are clean (kept indoors when not in use) and I have no idea what this mark is.

It looks like a black smudge (not bird poo) almost like a charcoal smudge? had caught it but it won't come out.

I've tried a general purpose Stain Devil which usually is pretty good on anonymous marks, have washed it again with a stain remover (ariel's one) rubbed into it and washed, still there. Tried Ace laundry bleach (again rubbed into it and washed) and no joy.

I use washing powder with Soda Crystals in most washes anyway, and am now at a loss as to what to try.

Any ideas? Thanks :)

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