R85 help please! executors estate

Hi,
Recently my grandma passed away and I am the executor of her estate.
Probate has just been granted last week and I have frozen all her accounts she had with Barclays.
Her estate consists on money only. Around £130,000 in various accounts.
Today I receive a form from barclays entitled R85 'getting your interest without tax taken off'
My simple question is, what is this form for? Do I need to fill it in?
I am clueless, and as its the weekend now its too late to phone anyone.
Any help would be gratefully received.

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